Acta Scientific Applied Physics

Review Article Volume 2 Issue 12

Surface Morphology of Polymers Examined by Atomic Force Microscopy

Péricles Lopes Santana*, José Roberto R Bortoleto, Nilson Cristino da Cruz, Elidiane Cipriano Rangel and Steven F Durrant

Universidade Estadual Paulista – UNESP Laboratorio de Plasmas Tecnologicos, Sorocaba, SP, Brasil

*Corresponding Author: Péricles Lopes Santana, Universidade Estadual Paulista – UNESP Laboratorio de Plasmas Tecnologicos, Sorocaba, SP, Brasil.

Received: September 09, 2022; Published: November 07, 2022

Abstract

In this article we introduce some studies of surface morphology in polyolefins, including commercial polymers. Atomic Force Microscopy (AFM) was used to examine the surface roughness of the pristine and plasma-treated samples. A polymer surface in a plasma is exposed to a broad spectrum of ions, electrons and radicals, which cause sputtering and etching and, consequently, increases surface roughness and induce changes in surface chemistry. Today, AFM, is one of the foremost tools for imaging, measuring and manipulating the surface of materials at the nanoscale, being useful in diverse areas such as materials and life science and in engineering, revealing surface roughness, RRMS above 1 nm and below 100 nm for the polymers examined by an Atomic Force Microscope at non contact mode.

Keywords: Polymers; Surface Morphology; AFM

References

  1. Schlüter S., et al. “Pore‐scale displacement mechanisms as a source of hysteresis for two‐phase flow in porous media”. Water Resources Research3 (2016): 2194.
  2. Geistlinger H., et al. “Impact of surface roughness on capillary trapping using 2D-micromodel visualization experiments”. Transport in Porous Media1 (2016): 207.
  3. Moreno L and Babadagli T. “Multilayer organic deposition on the rock surface with different wettabilities during solvent injection for heavy‐oil recovery”. The Canadian Journal of Chemical Engineering4 (2015): 664.
  4. Svorcík V., et al. “From gold nano-particles through gold nano-wire to gold nano-layers on substrate”. In: Chow PE, editor. Gold nanoparticles: properties, characterization and fabrication. Nova Sci. Publ: New York. 1 (2010).
  5. Acáková L and Svorcík V. “Cell colonization control by physical and chemical modification of materials”. In: Kimura D, editor. Cell growth processes: new Nova Sci. Publ. New York, 5 (2008).
  6. Inagaki N. “Plasma-Surface Modification and Plasma Polymerisation, Technomic, Lancaster”. CRC Press, Boca Raton, PA, 1 (1995).
  7. Lai J., et al. “Study on hydrophilicity of polymer surfaces improved by plasma treatment”. Applied Surface Science, Amsterdam. 252.10 (2006): 3375.
  8. Choi Y., et al. “Characteristics of atmospheric pressure N2cold plasma torch using 60-Hz AC power and its application to polymer surface modification”. Surface and Coatings Technology 1-3 (2005): 19.
  9. Kotál V., et al. “Gold Coating of Poly (ethylene terephthalate) Modified by Argon Plasma”. Plasma Processes and Polymers 4:69 (2007).
  10. Boyd RD., et al. “Atmospheric Nonequilibrium Plasma Treatment of Biaxially Oriented Polypropylene”. Macromolecules 30 (1997): 5429.
  11. Rockova ́K., et al. “Bio-compatibility of ion beam-modified and RGD-grafted polyethylene”. Nuclear Instruments and Methods in Physics Research Section B 3 (2004): 225.
  12. Sˇvorcı ́KV., et al. “Adhesion and proliferation of keratinocytes on ion beam modified polyethylene”. Journal of Materials Science: Materials in Medicine 11 (2000): 655.
  13. Svorcík V., et al. “Modification of surface properties of high and low density polyethylene by Ar plasma discharge”. Polymer Degradation and Stability 6 (2006): 1219.
  14. Tahara M., et al. “Improvement in adhesion of polyethylene by glow-disc harge plasma”. Surface and Coatings Technology 174-175 (2003): 826.
  15. Gerenser L J. “XPS studies of in situ plasma-modified polymer surfaces”. Journal of Adhesion Science and Technology 7 (1993): 1019.
  16. Selli E., et al. “Synthesis and characterisation of end-functionalised poly (N-vinylpyrrolidone) additives by reversible addition-fragmentation transfer polymerization”. Journal of Materials Chemistry 11 (2001): 1985.
  17. Hegemann D., et al. “Plasma treatment of polymers for surface and adhesion improvement”. Nuclear Instruments Methods B. 208 (2003): 281.
  18. Maddison DS and Unsworth J. “Optimization of synthesis conditions of polypyrrole from aqueous solutions”. Synthetic Metals 1 (1989): 47.
  19. Balu B., et al. “Fabrication of “Roll-off” and “Sticky” Superhydrophobic Cellulose Surfaces via Plasma Processing”. Langmuir9 (2008): 4785.
  20. Beake BD., et al. "Scanning force microscopy investigation of poly (ethylene terephthalate) modified by argon plasma treatment". Materials Chemistry 8 (1998): 1735.
  21. N Vandencasteele., et al. "Selected Effect of the Ions and the Neutrals in the Plasma Treatment of PTFE Surfaces: An OES‐AFM‐Contact Angle and XPS Study“. Plasma Processes and Polymers 6 (2005): 493-500.
  22. Teshima, K., et al. "Ultra-Water-Repellent Poly (ethylene terephthalate) Substrates". Langmuir25 (2003): 10624.
  23. Powell H M and Lannutti JJ. "Nanofibrillar Surfaces via Reactive Ion Etching“. Langmuir21 (2003): 9071.
  24. Di Mundo R., et al. “Influence of Chemistry on Wetting Dynamics of Nanotextured Hydrophobic Surfaces”. Langmuir7 (2010): 5196.
  25. Leitel R., et al. “Broadband Antireflective Structures on PMMA by Plasma Treatment”. Plasma Processes and Polymer 4 (2007): 878.
  26. Youngblood J P and McCarthy T. “Ultrahydrophobic Polymer Surfaces Prepared by Simultaneous Ablation of Polypropylene and Sputtering of Poly (tetrafluoroethylene) Using Radio Frequency Plasma”. Journal of Macromolecules20 (1999): 6800.
  27. Manca M., et al. “Influence of Chemistry and Topology Effects on Superhydrophobic CF4-Plasma-Treated Poly (dimethylsiloxane) (PDMS)”. Langmuir5 (2008): 1833.
  28. Tsougeni K., et al. “Control of Nanotexture and Wetting Properties of Polydimethylsiloxane from Very Hydrophobic to Super‐Hydrophobic by Plasma Processing”. Plasma Processes and Polymers 4 (2007): 398.
  29. Tserepi A., et al. “Nanotexturing of poly (dimethylsiloxane) in plasmas for creating robust super-hydrophobic surfaces”. Nanotechnology 17 (2006): 3977.
  30. Morber JR., et al. “Wafer‐Level Patterned and Aligned Polymer Nanowire/Micro‐ and Nanotube Arrays on any Substrate”. Advances in Material 21 (2009): 2072.
  31. Powell HM., et al. “Nanotopographic Control of Cytoskeletal Organization”. Langmuir11 (2006): 5087.
  32. Northen M T and Turner K L. “A batch fabricated biomimetic dry adhesive”. Nanotechnology 16 (2005): 1159.
  33. Koch K and Barthlott W. “Droplets on Superhydrophobic Surfaces: Visualization of the Contact Area by Cryo-Scanning Electron Microscopy”. Philosophical Transactions of the Royal Society A 367 (2009): 1487.
  34. Guo Z and Liu W. “Biomimic from the superhydrophobic plant leaves in nature: Binary structure and unitary structure”. Plant Science6 (2007): 1103.
  35. Barthlott W and Neinhuis C. “Purity of the sacred lotus, or escape from contamination in biological surfaces”. Plant Science1-8 (1997): 1.
  36. Li Y and Liu F. “A facile layer-by-layer deposition process for the fabrication of highly transparent superhydrophobic coatings”. 19 (2009): 2730.
  37. Yang C., et al. “Effect of upper contact line on sliding behavior of water droplet on superhydrophobic surface”. Chinese Science Bulletin 54 (2009): 727.
  38. d’Agostino R., et al. “Plasma Processes and Polymers”. Wiley VCH: New York, (2005).
  39. Järnström J., et al. “Roughness of pigment coatings and its influence on gloss”. Applied Surface Science18 (2008): 5741.
  40. Li J., et al. “In situ AFM study of the surface morphology of polypyrrole film”. Synthetic Metals 2 (1995): 127.
  41. Lee EH., et al. “Effects of electronic and recoil processes in polymers during ion implantation”. Journal of Materials Research 4 (1994): 1043-1050.
  42. Sant'Ana PL. “Polimeros tratados a plasma para dispositivos e embalagens”. Novas edições acadêmicas, 1 (2019).
  43. Sant'Ana PL. “Polymers Treated By Plasma For Optical Devices And Food Packaging”. Scholar’s Press, 1 (2018).
  44. Hayder Lateef Radhi Al-Maliki. “Adhesive and tribological behaviour of cold atmospheric plasma-treated polymer surfaces”. Szent Istvan University, Gödöllő, 1 (2018).
  45. Stout K J., et al. “The development of methods for the characterization of roughness in three dimensions”. Commission of the European Communities 1 (1993).
  46. Blunt L and Jiang X. “Advanced techniques for the assessment of surface topography, Development of a basis for 3D surface texture standards “SURFSTAND”. Chapter 2.1 (2003): 355.
  47. Miyoshi K. “Surface Characterization Techniques: An Overview”. NASA Technical Report NASA/TM-2002-211497 (2013).
  48. Raghavendra N V and Krishnamurthy L. “Metrology of surface finish, in Engineering Metrology and Measurements (Oxford University Press)” Ch. 9. (2013).
  49. Petropoulos GP., et al. “Surface Texture Characterization and Evaluation Related to Machining, in Surface Integrity in Machining”. ed. J.P. Davim, Springer, Ch. 2 (2010).
  50. Galanzha EI., et al. “In vivo magnetic enrichment and multiplex photoacoustic detection of circulating tumour cells”. Nature Nanotechnology 4 (2009): 855.
  51. Jathoul AP., et al. “Deep in vivo photoacoustic imaging of mammalian tissues using a tyrosinase-based genetic reporter”. Nature Photonics 9 (2015): 239.
  52. Pu K Y., et al. “Semiconducting polymer nanoparticles as photoacoustic molecular imaging probes in living mice”. Nature Nanotechnology 9 (2014): 233.
  53. Razansky D., et al. “Multispectral opto-acoustic tomography of deep-seated fluorescent proteins in vivo”. Nature Photonics 3 (2009): 412.
  54. Shelton R L., et al. “Volumetric imaging of erythrocytes using label‐free multiphoton photoacoustic microscopy”. Journal of Biophotonics 7 (2014): 834.
  55. Wang L V and Hu S. “Photoacoustic tomography: in vivo imaging from organelles to organs”. Science6075 (2012): 1458.
  56. Yao J J., et al. “High-speed label-free functional photoacoustic microscopy of mouse brain in action”. Nature Methods 12 (2015): 407.
  57. Yao J J., et al. “Photoimprint photoacoustic microscopy for three-dimensional label-free subdiffraction imaging”. Physical Review Letters 112 (2014): 014302.
  58. Ruggeri FS., et al. “Infrared nanospectroscopy characterization of oligomeric and fibrillar aggregates during amyloid formation”. Nature Communication7831 (2015): 1.
  59. Khulbe KC., et al. “Surface morphology of homogeneous and asymmetric membranes made from poly (phenylene oxide) by tapping mode atomic force microscope”. Journal of Applied Polymer Science 59 (1996): 151.
  60. Boussu K., et al. “Roughness and hydrophobicity studies of nanofiltration membranesusing different modes of AFM”. Journal of Colloid and Interface Science 286 (2005): 632.
  61. Dazzi A., et al. “AFM-IR: Combining Atomic Force Microscopy and Infrared Spectroscopy for Nanoscale Chemical Characterization”. Applied Spectroscopy 12 (2012): 1365.
  62. Morris HS., et al. “Quantifying the Hygroscopic Growth of Individual Submicrometer Particles with Atomic Force Microscopy”. Analytical Chemistry 7 (2016): 3647.
  63. Morris HS., et al. “Humidity-dependent surface tension measurements of individual inorganic and organic submicrometre liquid particles”. Chemical Science5 (2015): 3242.
  64. Hritz A D., et al. “A method for the direct measurement of surface tension of collected atmospherically relevant aerosol particles using atomic force microscopy”. Atmospheric Chemistry and Physics 15 (2016): 9761.
  65. Krueger BJ., et al. “Formation of Microcrystals, Micropuddles, and Other Spatial Inhomogenieties in Surface Reactions under Ambient Conditions:  An Atomic Force Microscopy Study of Water and Nitric Acid Adsorption on MgO (100) and CaCO3 (101̄4)”. Langmuir19 (2005): 8793.
  66. Khulbe KC and Matsuura “Characterization of synthetic membranes by Raman spectroscopy, electron spin resonance, and atomic force microscopy; a review”. Polymer 41.5 (2000): 1917.
  67. Gould SAC., et al. “Influence of substrate morphology on the cohesion and adhesion of thin PECVD oxide films on semi‐crystalline polymers”. Journal of Applied Polymer Science 65 (1997): 1237.
  68. W R Nidal., et al. “Visualisation of an ultrafiltration membrane by non-contact atomic force microscopy at single pore resolution”. Journal of Membrane Science 2 (1992): 229.
  69. Fritzsche AK., et al. “The surface structure and morphology of polyvinylidene fluoride microfiltration membranes by atomic force microscopy”. Journal of Membrane Science1-2 (1992): 65.
  70. Fritzsche AK., et al. “The structure and morphology of the skin of polyethersulfone ultrafiltration membranes: A comparative atomic force microscope and scanning electron microscope study”. Journal of Applied Polymer Science 45 (1992): 1945.
  71. Fritzsche AK., et al. “The surface structure and morphology of polyacrylonitrile membranes by atomic force microscopy”. Journal of Applied Polymer Science 1-2 (1992): 109.
  72. Fritzsche A K., et al. “Molecular dynamics simulations of the transport of water-ethanol mixtures through polydimethylsiloxane membranes”. Journal of Membrane Science 5 (1997): 1031.
  73. Khulbe K C., et al. “Characterization of Polyphenylene Oxide and Modified Polyphenylene Oxide Membranes”. Journal of Membrane Science 2 (1997): 211.
  74. Zˇukiene K., et al. “AFM lateral force imagining of modified polychloroprene: A study based on roughness analysis”. Applied Surface Science 253 (2006): 966.
  75. Dienwiebel M., et al. “Design and performance of a high-resolution frictional force microscope with quantitative three-dimensional force sensitivity”. Review of Scientific Instruments 76 (2005): 043704.
  76. Sant’Ana PL., et al. “Análise comparativa entre o grau de molhabilidade dos polímeros reciclados PVC e PET tratados por imersão ou deposição de filmes orgânicos em plasmas fluorados”. Revista Brasileira de Aplicações de Vácuo 3 (2019): 120.
  77. Sant’Ana PL., et al. “Study of wettability and optical transparency of pet polymer modified by plasma immersion techniques”. Revista Brasileira de Aplicações de Vácuo 2 (2017): 68.
  78. He XM., et al. “Optical and tribological properties of diamond-like carbon films synthesized by plasma immersion ion processing”. Thin Solid Films 355/356 (1999): 167.
  79. Jinlong Z., et al. “Superhydrophobic of polymer films via fluorine atoms covalent attachment and surface nano-texturing”. Journal of Fluorine Chemistry 200 (2017): 123.
  80. Sant’Ana PL., et al. “Surface Properties and Morphology of PET Treated by Plasma Immersion Ion Implantation for Food Packaging”. Nanomedicine and Nanotechnology Open Access 3 (2018): 1.
  81. Sant’Ana P L., et al. “Surface Properties of PET Polymer Treated by Plasma Immersion Techniques for Food Packaging”. International Journal of Nano Research 1 (2018): 33.
  82. Jinlong Z., et al. “Superhydrophobic of polymer films via fluorine atoms covalent attachment and surface nano-texturing”. Journal of Fluorine Chemistry 200 (2017): 123-132.
  83. Chu PK., et al. “Third-generation plasma immersion ion implanter for biomedical materials and research”. Review of Scientific Instruments 3 (2001): 1660-1665.
  84. Guruvenket S., et al. “Plasma surface modification of polystyrene and polyethylene”. Applied Surface Science 1-4 (2004): 278-284.
  85. Triandafillu K., et al. “Adhesion of pseudomonas aeruginosa strains to untreated and oxygen-plasma treated poly (vinyl chloride) (PVC) from endotracheal intubation devices”. Biomaterials 8 (2003): 1507-1518.
  86. Park YW and Inagaki N. “Surface modification of poly (vinylidene fluoride) film by remote Ar, H2, and O2 plasmas”. Polymer5 (2003): 1569-1575.
  87. J Brutscher., et al. “Sheath dynamics in plasma immersion ion implantation”. Plasma Sources Science and Technology 5 (1996): 54.
  88. AP Kharitonov., et al. “Comparison of the surface modifications of polymers induced by direct fluorination and rf-plasma using fluorinated gases”. Journal of Fluorine Chemistry 165 (2014): 49-60.
  89. I G Broun., et al. “Metal ion implantation: Conventional versus immersion. MacGill”. Journal of Vacuum Science and Technology B12 (1994): 823.
  90. Junkar I., et al. “The role of crystallinity on polymer interaction with oxygen plasma”. Process Polymer 6 (2009): 667.
  91. Wagner P., et al. “Quantitative Assessment to the Structural Basis of Water Repellency in Natural and Technical Surfaces”. Journal of Experimental Botany 54 (2003): 1295.
  92. Okuji S., et al. “Surface modification of polymeric substrates by plasma-based ion implantation”. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms1-2 (2006): 353.
  93. Marais S., et al. “Effect of a low-pressure plasma treatment on water vapor diffusivity and permeability of poly (ethylene-co-vinyl alcohol) and polyethylene films”. Surface and Coatings Technology 3-4 (2006): 868.
  94. Tahara M., et al. “Improvement in adhesion of polyethylene by glow-discharge plasma”. Surface and Coatings Technology 174-175 (2003): 826.
  95. Švorčík V., et al. “Modification of surface properties of high and low density polyethylene by Ar plasma discharge”. Polymer Degradation and Stability 6 (2006): 1219.
  96. Jones V., et al. “Development of Poly (propylene) Surface Topography During Corona Treatment”. Plasma Process and Polymer7 (2005): 547.
  97. Karade Y., et al. “Determination of Cross-Link Density in Ion-Irradiated Polystyrene Surfaces from Rippling”. Langmuir5 (2009): 3108.
  98. Karade Y., et al. “Oriented nanometer surface morphologies by thermal relaxation of locally cross-linked and stretched polymer samples”. Microelectronic Engineering 5-8 (2007): 797.
  99. Sanchis M R., et al. “Surface modification of low density polyethylene (LDPE) film by low pressure O2plasma treatment”. European Polymer Journal 7 (2006): 1558.
  100. Mirabedini SM., et al. “Effect of low-pressure O2and Ar plasma treatments on the wettability and morphology of biaxial-oriented polypropylene (BOPP) film”. Progress in Organic Coatings 2, (2007): 105.
  101. Slepička P., et al. “Argon plasma irradiation of polypropylene”. Nuclear Instruments and Methods 11-12 (2010): 2111.
  102. Švorčík V., et al. “Modification of surface properties of high and low density polyethylene by Ar plasma discharge”. Polymer Degradation and Stability 6 (2006): 1219.
  103. Švorčík V., et al. “Ablation and water etching of poly (ethylene) modified by argon plasma”. Polymer Degradation and Stability 9 (2007): 1645.
  104. Reznickova A., et al. “Comparison of glow argon plasma-induced surface changes of thermoplastic polymers”. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 2 (2011): 83.
  105. Crucho C I., et al. “Surfactant-free polymeric nanoparticles composed of PEG, cholic acid and a sucrose moiety”. Journal of Materials Chemistry B25 (2014): 3946.
  106. Chen J., et al. “Applications of atomic force microscopy in materials, semiconductors, polymers, and medicine: A minireview”. Instrumentation Science and Technology6 (2020): 667.
  107. Lopez R., et al. “Robust Hydrophobic Coatings Using Polymer Blends for the Surface Protection of Marble”. Colloids and Surfaces A: Physicochemical and Engineering Aspects 599 (2020): 124796.
  108. Waranpillai JP., et al. “Intermolecular hydrogen bonding in developing nanostructured epoxy shape memory thermosets: Effects on morphology, thermo-mechanical properties and surface wetting”. Polymer Testing 81 (2020): 10627.
  109. Hasa E., et al. “Manipulation of crosslinking in photo-induced phase separated polymers to control morphology and thermo-mechanical properties”. Polymer 202 (2020): 122699.
  110. Bouali AB., et al. “Nanoscale mechanical properties of chitosan hydrogels as revealed by AFM”. Progress in Biomaterials 9 (2020): 187.
  111. Tamburaci S., et al. “Chitosan-hybrid poss nanocomposites for bone regeneration: The effect of poss nanocage on surface, morphology, structure and in vitrobioactivity”. International Journal of Biological Macromolecules 142 (2020): 643.
  112. Hu J and Zhu S. “Microscopy of Shape Memory Polymers, Polymer Blends, and Composites”. In: Parameswaranpillai J.; Siengchin S.; George J.; Jose, S. (eds) Shape Memory Polymers, Blends and Composites. Advanced Structured Materials 115 (2020): 95.
  113. Wu F., et al. “Tailoring the toughness of sustainable polymer blends from biodegradable plastics via morphology transition observed by atomic force microscopy”. Polymer Degradation and Stability 173 (2020): 109066.
  114. Grytsenko K., et al. “Influence of different aligning surfaces on the morphology of dichroic squaraine films”. Polymer Bulletin 78 (2021): 1313.
  115. Nguyen-Tri P., et al. “Recent Applications of Advanced Atomic Force Microscopy in Polymer Science: A Review”. Polymers 12 (2020): 1142.
  116. Sadeghi K and Seo J. “Photografting of p-anisidine-glycidyl methacrylate onto polymeric substrate for developing free-radical scavenging films”. Progress in Organic Coatings 149 (2020): 105925.
  117. Ang M B M Y., et al. “Surface Properties, Free Volume, and Performance for Thin-Film Composite Pervaporation Membranes Fabricated through Interfacial Polymerization Involving Different Organic Solvents”. Polymers 10 (2020): 2326.
  118. Chan CM., et al. “Polymer surface modification by plasmas and photons”. Surface Science Reports 24 .1-2 (1996): 1.
  119. Grace JM and Gerenser LJ. “Plasma Treatment of Polymers”. Journal of Dispersion Science and Technology 24 (2003): 341.

Citation

Citation: Péricles Lopes Santana., et al. “Surface Morphology of Polymers Examined by Atomic Force Microscopy". Acta Scientific Applied Physics 2.12 (2022): 04-20.

Copyright

Copyright: © 2022 Péricles Lopes Santana., et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.



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