Comparative Study of Intermolecular Interaction in Binary Liquid Mixture
Containing (Cyclic Ether + 1-Octanol) at Different Temperature
Dhirendra Kumar Sharma1* and Ranjana Singh Tomar2
1Department of Chemistry, Institute of Basic Science, Bundelkhand University,
Jhansi (U.P), India
2Department of Chemistry, Technocrats Institute of Technology, Bhopal (M.P.), India
*Corresponding Author: Dhirendra Kumar Sharma, Department of Chemistry,
Institute of Basic Science, Bundelkhand University, Jhansi (U.P), India
Received:
June 25, 2024; Published: September 06, 2024
Abstract
Density (ρ), speed of sound (u), and viscosity for the binary mixture 1,4-Dioxane (1) + 1-Octanol (2) were measured over the
whole composition range at temperatureT = (298.15, 303.15 and 305.15) K. From the experimental data excess molar volume (VE),
excess adiabatic compressibility excess viscosity excess intermolecular free length (Pi E) were calculated. These results have been fitted to the Redlich-Kister polynomial equation. Excess molar volume (VE), excess adiabatic compressibility , excess viscosity , excess intermolecular free length and excess internal pressure (Pi E) were
found to be negative for all temperatures. The thermodynamic properties have been discussed in term of nature of molecular interac
tions between the components of the mixture.
Keywords: Speed of Sound; Density; Viscosity; Binary Liquid Mixtures; Internal Pressure; Molar Volume; Intermolecular Free Length
and Redlich-Kister Polynomial Equation
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